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matrix

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Hi there,

I would like to know what does 10W40(semi-synthetic engine oil) mean? Does it make any difference in seasons? What is the best option for each season- winter/summer?
Thx for replies
 

turnipsock

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The number with the 'W' referes to the thickness when the oil is cold. A low number is good as it flys round the engine before you have finished your mug of tea so you can get both hands on the wheel a lot quicker to get on with some serious driving.
 

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Err yes, it goes something like this:

What is this thing called viscosity?

It?s written on every can of oil and it?s the most important visible characteristic of an oil.

The viscosity of an oil tells you how it reacts in certain circumstances and how it performs as a lubricant.

When a oil is subjected to external forces, it resists flow due to internal molecular friction and viscosity is the measure of that internal friction. Viscosity is also commonly referred to as the measurement of the oils resistance to flow.

There are two methods of viewing an oils resistance to flow. Firstly there is Kinematic Viscosity which is expressed as units indicating the flow of volume over a period of time and this is measured in centistokes (cSt).
An oils viscosity can also be viewed by measured resistance. This is known as Apparent Viscosity and it is measured in centipoises (cP).

However in the real world an oils viscosity is also referred to in such terms as thin, light and low etc. This suggests that the oil flows or circulates more easily. Conversly, terms such as heavy and high etc suggest the fluid has a stronger resistance to flow.

The reason for viscosity being so important is because it is directly related to the oils load-carrying ability - The greater an oils viscosity, the greater the loads that it can withstand. (It must be added when new not over a period of time as all oils ?shear down? with use)

An oil must be capable of separating the moving parts in your engine at the operating temperature. On the basis that an oils viscosity is related to its load carrying ability, you could be fooled into thinking that ?thicker? oils are better at lubricating but, you?d be wrong in this assumption. The fact is that in the wrong application a high viscosity oil can be just as damaging as using a low viscosity oil.

The use of an oil that?s too ?thin? can cause metal-to-metal contact, poor sealing and increased oil consumption and conversely, an oil that?s too ?thick? can cause increased friction, reduced energy efficiency, higher operating temperatures, and poor cold starts in cold temperatures.

It is very important that you select the correct oil, not too ?light? or too ?heavy? and your Owners Handbook is a very good place to start as it lists the temperatures and options.

Oils thicken at low temperatures and thin as the temperature increases. The actual rate of change is indicated by their viscosity index (this number normally listed on the oils technical data sheet indicates the degree of change in viscosity of an oil within a temperature range, currently 40-100 degrees centigrade)

An oil with a high viscosity index, will normally behave similarly at these two temperatures but an oil with a low viscosity index will behave quite differently. It will become very fluid, thin and pour easily at high temperatures. A higher index is better!

Multi-grade oils are designed to perform at high and low temperatures by adding polymers to a base oil (5w,10w, 15w etc) which are heat sensitive and ?uncoil? to maintain the higher viscosity sae 30,40,50 etc. This means that the oil can be used ?all year round? rather than using different oils for summer and winter.

It is important to understand that the selection of the correct oil for your car is not just guesswork, you must consider the temperatures at which you need the oil to operate a 0w, 5w oil is better for cold starts as the oil circulates more easily when it?s cold and is able to flow around the engine more easily and quickly, offering protection at the critical moments following cold engine start-up. These oils are also known to give better fuel economy and engine performance.

Finally, all oils ?shear? or thin down with use and this means that an oil that started life as a 10w-40 will with use become a 10w-20. The period of time this takes depends on the type and quality of the oil. The most ?shear stable? oils are proper Synthetics, either PAO (Poly Alph Olefins) or Esters which have very high thermal stability. They are in general of the more expensive variety but last longer and give the best levels of protection.

Cheers
Simon
 

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And if that doesn't answer your question matrix,, nothing will. :lol:

Stu
 

landover

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turnipsock said:
The number with the 'W' referes to the thickness when the oil is cold. A low number is good as it flys round the engine before you have finished your mug of tea so you can get both hands on the wheel a lot quicker to get on with some serious driving.

Or in your case On your Bike. How do i know that???????????
 
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matrix

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wow...

Oilman,

Thank you for your deep and scientific answer...
 

squealinneil

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oilman,
Jeez!
Tell me this. What will happen to my 90K mile '82 230E, always run on mineral oil, if I switch to semi- syn? Should I stick with the same grade?
Thanks.
 

oilman

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Changing to semi-synthetic is no problem, if you let me know the model and year I'll look up the most suitable viscosity.

Cheers
Simon
 

squealinneil

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Thanks,

1982 230E. 90,000 miles, poo brown in colour but a lovely 1 owner for 23 years car nonetheless!

How long will semi syn be good for?

I have friends who foolishly watch their money depreciate hourly by buying new Jags, Audis & the like. They say their cars can go 10, 15 or even 20K miles between oil changes. Sounds mad to me. I've always worked on the theory oil is cheap, engines are expensive. What do you think about these big mileages between changes.

I change ALL the fluids every two years - brake, tranny, diff, - you name it. Is that unnecessary?
Many thanks in advance.
 

oilman

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squealinneil said:
Thanks,

1982 230E. 90,000 miles, poo brown in colour but a lovely 1 owner for 23 years car nonetheless!

How long will semi syn be good for?

I have friends who foolishly watch their money depreciate hourly by buying new Jags, Audis & the like. They say their cars can go 10, 15 or even 20K miles between oil changes. Sounds mad to me. I've always worked on the theory oil is cheap, engines are expensive. What do you think about these big mileages between changes.

I change ALL the fluids every two years - brake, tranny, diff, - you name it. Is that unnecessary?
Many thanks in advance.

Some of these new engines do go 10,000 miles plus on one oil change, however they use very thin long life oils which would not be sutable for an older car.

For your car a 10w-40 semi synthetic with oil changes around 6,000 miles if you use a quality one.

There is no harm changing all the fluids every two years, more people should do it.

Cheers

Simon.
 
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matrix

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One more question... Whats the difference beween synthetic and semi-synthetic motor oil? I 've just bought 1992 200E with 100k miles. What oil do you recommend?
 

oilman

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matrix said:
One more question... Whats the difference beween synthetic and semi-synthetic motor oil? I 've just bought 1992 200E with 100k miles. What oil do you recommend?

Semi synthetics are either hydrocrakced mineral oil or blends of mineral and synthetic, a full synthetic or true synthetic has no petroleum base stock at all.

Perhaps this will help.

SYNTHETICS vs MINERALS

Oil is the lifeblood of your vehicle's engine. For decades conventional petroleumoils have been providing adequate protection for all of our vehicles.

The key word here is adequate. Petroleum oils, for the most part, have done an adequate job of protecting our engines from break down. If you change it often enough, you can be relatively sure that your car will last 100,000 to 150,000 miles without a serious engine problem - maybe even longer.

The real question is, why settle for adequate when something better has been available for about 30 years?

Today's engines are built for better performance, and, although petroleum oils are designed for better protection and performance today than they were 10 or 20 years ago, there is only so much that can be done. Today's engines need high performance lubricants, and the only true ones available are synthetics.

Conventional petroleum oils are insufficient for use in today's vehicles primarily because they are manufactured from a refined substance, contain paraffins (wax), sulfur, nitrogen, oxygen, water, salts and certain metals. All of these contaminants must be refined out of the basestock in order for it to be useful for use within a lubricant.

Unfortunately, no refining process is perfect. Impurities will always remain when any refining process is done. It simply isn't economical to continue to refine the oil again and again to remove more impurities. If this was done, petroleum oils would cost as much as synthetic oils do.

There are many components of petroleum oil basestocks which are completely unnecessary for protecting your engine. They do absolutely nothing to enhance the lubrication properties of the oil. In fact, most of these contaminants are actually harmful to your oil and your engine.

Some of the chemicals in conventional petroleum lubricants break down at temperatures well within the normal operating temperature range of your engine. Others are prone to break down in these relatively mild temperatures only if oxygen is present. But, this is invariably the case anyway, especially since oxygen is one of the contaminants within petroleum basestocks.

These thermally and oxidatively unstable contaminants do absolutely nothing to aid in the lubrication process. They are only present in conventional petroleum oils because removing them would be impossible or excessively expensive.

When thermal or oxidative break down of petroleum oil occurs, it leaves engine components coated with varnish, deposits and sludge. In addition, the lubricant which is left is thick, hard to pump and maintains little heat transfer ability.

In addition, petroleum oils contain paraffins which cause dramatic oil thickening in cold temperatures. Even with the addition of pour point depressant additives, most petroleum oils will begin to thicken at temperatures 10 to 40 degrees warmer than synthetic oils.

As a result, petroleum lubricants will not readily circulate through your engine's oil system during cold weather. This may leave engine parts unprotected for minutes after startup. Obviously, significant wear can occur during this time frame.

Even when all conditions are perfect for conventional oils to do their job, they fall far short of synthetic oils. Part of the problem is that (because of their refined nature) petroleum oils are composed of molecules which vary greatly in size. As the oil flows through your vehicle's lubrication system, the small, light molecules tend to flow in the center of the oil stream while the large, heavy ones adhere to metal surfaces where they create a barrier against heat movement from the component to the oil stream. In effect, the large, heavy molecules work like a blanket around hot components.

There is also another effect of the non-uniformity of petroleum oil molecules which reduces their effectiveness. Uniformly smooth molecules slip over one another with relative ease. This is not the case with molecules of differing size.
Theoretically, it might be somewhat similar to putting one layer of marbles on top of another (if this could easily be done). If the marbles were all of the same size, they would move over one another fairly easily. However, if they were all of differing sizes, the result would be much less efficient.

In the case of petroleum oils this inefficiency leads, ironically, to added friction in the system (the very thing that lubricants are supposed to reduce). Hence, petroleum oils are only marginally capable of controlling heat in your engine. Considering that motor oil does nearly 50% of the cooling of your engine, that's not a good thing. But,

This being said, petroleum oils are ?adequate? for the purpose of protecting your engine, if you don't mind a shorter vehicle lifespan, inconvenient oil changes, or decreased engine performance. Under normal circumstances, most vehicles lubricated with petroleum oil should run satisfactorily for 100,000 to 150,000 miles without serious incidence.

If you like the hassle of changing your oil regularly, and you are only looking for marginal performance for the next 100,000 miles or so, petroleum oils are definitely the way to go.

Assuming that you don't relish the idea of changing your oil every 2,000 miles or and are looking to keep your ?pride and joy? in tip-top condition then these are the main areas where synthetic oils surpass their petroleum counterparts.

Oil drains can be extended
Vehicle life can be extended
Costly repairs can be reduced
Fuel mileage can be improved
Performance can be improved

Synthetic basestock molecules are pure and of uniform size. This is because synthetic basestocks are designed from the ground up with the sole purpose of protecting your engine. Nothing is added if it does not significantly contribute to the lubricating ability of the oil.
In addition, in top-quality synthetics, no component is added which might be contaminated with any substance that might lessen the lubricating qualities of the oil. In other words, manufacturers of these premium synthetics implement very strict quality control measures to insure no contamination.

Not only that, synthetic basestocks are designed so that the molecules are of uniform size and weight. In addition, synthetic basestock molecules are short-chain molecules which are much more stable than the long-chain molecules that petroleum basestocks are made of. This significantly adds to the lubricating qualities and stability of the oil.

EXTENDED OIL DRAINS
Stable Basestocks
Synthetic oils are designed from pure, uniform synthetic basestocks, they contain no contaminants or unstable molecules which are prone to thermal and oxidative break down.
Moreover, because of their uniform molecular structure, synthetic lubricants operate with less internal and external friction than petroleum oils which have the non-uniform molecular structure. The result is better heat control, and less heat means less stress to the lubricant.

Higher Percentage of Basestock
Synthetic oils contain a higher percentage of lubricant basestock than petroleum oils do.
This is because multi-viscosity oils need a great deal of pour point depressant and viscosity modifying additives in order to be sold as multi-viscosity oils.
Synthetic oils, require very little in the way of pour point depressants and viscosity
modifiers. Therefore, synthetic oils can contain a higher percentage of basestock, which actually does most of the lubricating anyway. More basestock leads to longer motor oil life.

Additives Used Up More Slowly
Petroleum basestocks are much more prone to oxidation than synthetic oils, oxidation inhibitors are needed in greater supply and are used up very quickly. Synthetic oils do oxidize, but at a much slower rate therefore, oxidation inhibiting additives are used up much more slowly.
Synthetic oils provide for better ring seal than petroleum oils do. This minimizes blow-by and reduces contamination by combustion by-products. As a result, corrosion inhibiting additives have less work to do and will last much longer than within a petroleum oil.

Excellent Heat Tolerance
Synthetics are simply more tolerant to extreme heat than petroleum oils are. When heat builds up within an engine, petroleum oils quickly begin to burn off. They volatize. In other words, the lighter molecules within petroleum oils turn to gas and what's left are the large petroleum oil molecules that are harder to pump.
Synthetics are resistant to this burn-off. They will tolerate much higher engine temperatures.

EXTENDED VEHICLE LIFE WITH FEWER REPAIRS
Heat Reduction
More often than not, vehicle life is determined by engine life. One of the major factors affecting engine life is component wear and/or failure, which is often the result of high temperature operation. The uniformly smooth molecular structure of synthetic oils gives them a much lower coefficient of friction (they slip more easily over one another causing less friction) than petroleum oils.
Less friction, of course, means less heat in the system. And, since heat is a major contributor to engine component wear and failure, synthetic oils significantly reduce these two detrimental effects.
In addition, because of their uniform molecular structure, synthetic oils do not cause the "blanket effect" which was mentioned earlier. Since each molecule in a synthetic oil is of uniform size, each is equally likely to touch a component surface at any given time, thus moving a certain amount of heat into the oil stream and away from the component. This makes synthetic oils far superior heat transfer agents than conventional petroleum oils.

Greater Film Strength
Petroleum motor oils have very low film strength in comparison to synthetics. The film strength of a lubricant refers to it's ability to maintain a film of lubricant between two objects when extreme pressure and heat are applied.
Synthetic oils will typically have a film strength of 500% to 1000% higher than petroleum oils of comparable viscosity. In fact, believe it or not, even though heavier weight oils typically have higher film strength than lighter weight oils, a 0w30 or 5w-40 weight synthetic oil will likely have higher film strength than a 15w40 or 20w50 petroleum oil.
Thus, even with a lighter weight oil, you can still maintain proper lubricity and reduce the chance of metal to metal contact when using a synthetic oil. Of course, that means that you can use oils that provide far better fuel efficiency and cold weather protection without sacrificing engine protection under high temperature, high load conditions. Obviously, this is a big plus, because you can greatly reduce both cold temperature start-up wear and high temperature/high load engine wear using the same low viscosity oil.

Engine Deposit Reduction
In discussing some of the pitfalls of petroleum oil use, engine cleanliness is certainly an issue. Petroleum oils tend to leave sludge, varnish and deposits behind after thermal and oxidative break down. They're better than they used to be, but it still occurs.
Deposit build-up leads to a significant reduction in engine performance and engine life as well as increasing the number of costly repairs that are necessary. Since synthetic oils have far superior thermal and oxidative stability than petroleum oils, they leave engines virtually varnish, deposit and sludge-free.

Better Cold Temperature Fluidity
Synthetic oils and other lubricants do not contain paraffins or other waxes which dramatically thicken petroleum oils during cold weather. As a result, they tend to flow much better during cold temperature starts and begin lubricating an engine almost immediately. This leads to significant engine wear reduction, and, therefore, longer engine life and fewer costly repairs.

IMPROVED FUEL MILEAGE AND PERFORMANCE
As indicated earlier, synthetic oils, because of their uniform molecular structure, are tremendous friction reducers. Less friction leads to increased fuel economy and improved engine performance.
Any energy released from the combustion process that would normally be lost to friction can now be transferred directly to the wheels, providing movement.
Vehicle acceleration becomes swifter and more powerful while using less fuel in the process.
The uniform molecular structure of synthetic oils has another performance enhancing benefit as well. In a petroleum oil, lighter molecules tend to boil off easily, leaving behind much heavier molecules which are difficult to pump. Certainly, the engine loses more energy pumping these heavy molecules than if it were pumping lighter ones.
Since synthetic oils have more uniform molecules, fewer of these molecules tend to boil off.
More importantly, when they do, the molecules which are left are of the same size and pumpability is not affected.

Hope this helps.

Cheers

Simon.
 

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Changing the oil?

OK OK I know this looks like a dumb@ss question . . but what is the best process for changing the engine oil in a car?
I currently have a 1992 230CE.

Are the engine oil flushing solutions a good option? Or is is better to flush the engine out by topping it up again with the original oil a couple of times and letting it run for a while?

I've had the car 9 months now and am considering a full fluid change, as I am unaware of when the last change was done.
Castrol GTX Magnatec 10w40 is what I used to top it up.
Is this a good oil for the car, I have been recommended Mobil 1 0w40 by my local garage.

Thanks
 

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Re: Changing the oil?

hitt said:
OK OK I know this looks like a dumb@ss question . . but what is the best process for changing the engine oil in a car?
I currently have a 1992 230CE.

Are the engine oil flushing solutions a good option? Or is is better to flush the engine out by topping it up again with the original oil a couple of times and letting it run for a while?

I've had the car 9 months now and am considering a full fluid change, as I am unaware of when the last change was done.
Castrol GTX Magnatec 10w40 is what I used to top it up.
Is this a good oil for the car, I have been recommended Mobil 1 0w40 by my local garage.

Thanks

Magnatec is not special at all, in fact I will not even stock it!

Flushing Procedure (Don?t use flushing oils or additives)

1. Warm up engine to get oil circulating
2. Turn off engine and drain old oil
3. Fill with new oil to minimum (you will be wasting this)
4. Warm up engine to get oil circulating
5. Turn off engine, drain new oil and change filter
6. Fill to marker on dipstick

Cheers

Simon.
 

squealinneil

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Oilman,
we're in your debt.

The amount of knowledge on the MB BBs is astonishing. I don't think I'll ever need to go near a dealership again!

"Magnatec is not special at all, in fact I will not even stock it!"

Is a cheaper, non advertised brand such as Comma or Synerg-G (as stocked by my local auto factors) OK?

What's the best 10-40 oil?
 

oilman

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squealinneil said:
Oilman,
we're in your debt.

The amount of knowledge on the MB BBs is astonishing. I don't think I'll ever need to go near a dealership again!

"Magnatec is not special at all, in fact I will not even stock it!"

Is a cheaper, non advertised brand such as Comma or Synerg-G (as stocked by my local auto factors) OK?

What's the best 10-40 oil?

If you are going to use comma or synerg then you may as well stick with magnatec.

You need a good brand name.

Castrol Performance 10w-40 (semi)
Total Quartz 7000 10w-40 (semi)
Fuchs Titan XTR 10w-40 (semi)
Motul 6100 Synergie 10w-40 (semi)

Fuchs Titan Unic Plus 10w-40 (pao synthetic)
Motul 300v Chrono 10w-40 (pao/ester synthetic)

To name a few.

Tech specs on these here http://www.opieoils.co.uk/lubricants.htm

Cheers

Simon.
 

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oilman

Mine is due for service, just wondering if which oil would be best for my C180 year 2000, is it 5w-40 or 0-40. Also do you think that merc garages really put the right oil i.e. claiming they put fully synthetic on your motor but the truth is they only use semi synthetic.
 

oilman

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W77 said:
oilman

Mine is due for service, just wondering if which oil would be best for my C180 year 2000, is it 5w-40 or 0-40. Also do you think that merc garages really put the right oil i.e. claiming they put fully synthetic on your motor but the truth is they only use semi synthetic.

Personally I'd use 5w-40 fully synthetic.

Cheers
Simon
 

oilman

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squealinneil said:
Oilman,

On another MB forum someone posted that Halford's are having a half price sale on their fully synthetic oil. About 15 quid for 5 litres. Are Halford's oils OK or would you abstain?

http://www.mbclub.co.uk/forums/showthread.php?p=98367#post98367

Thanks again for your expertise on matters oily.

I would steer clear as it's not a proper one but a hydrocracked mineral oil, yes it's cheap but you get what you pay for!

Cheers
Simon
 
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